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磺化酞菁镓的聚合及分解动力学研究
THE AGGREGATION AND KINETICS OF DECOMPOSITION REACTION OF Ga SULFOPHTHALOCYANINE
【摘要】 采用分光光度法研究了磺化酞菁镓在不同pH溶液中的二聚现象及在碱性溶液中的分解动力学,测定了二聚常数KD和分解速率常数kobs,结果表明:磺化酞菁镓的分解速度方程可表示为:-dcDdt=12.27cOH-cD,式中cD、cOH-分别为溶液中磺化酞菁镓二聚体和碱的浓度。
【Abstract】 The aggregation and kinetics of decomposition reaction of Gasulfophthalocyanine has been studied by electronic spectroscopy.The effects of pH on the aggregation are discussed.The experimental results show that the rate of decomposition reaction of Ga sulfophthalocyanine can be expressed as follow: - d c M d t=12 279c D c OH - Where c D and c OH - concentration of GA sulfophthalocyanine and OH - respectively.
【基金】 国家、江苏省自然科学基金
- 【文献出处】 光谱学与光谱分析 ,SPECTROSCOPY AND SPECTRAL ANALYSIS , 编辑部邮箱 ,1997年06期
- 【分类号】O63
- 【被引频次】2
- 【下载频次】57