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三氮吲哚嗪对增感染料吸收光谱和荧光谱的影响

INFLUENCES OF TERRAAZAINDENE ON ABSORPTION SPECTRA AND FLUORESCENCE SPECTRA OF SENSITIZING DYES

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【作者】 郑均平陈萍盛丽琴郑德水

【Author】 ZHENG Junping,CHEN Ping,SHENG Liqing and ZHENG Deshui Institute of Photographic Chemistry,Academia Sinica,100101 Beijing

【机构】 中国科学院感光化学研究所

【摘要】 本文研究了三氮吲哚嗪(TAI)对三种卤化银乳剂增感染料水溶液的吸收光谱和荧光光谱的影响。研究表明TAI能使这些染料的各吸收峰强度增强,对容易形成J聚集体的染料来说,更有利于其J态光谱吸收;当三氮吲哚嗪的浓度达到一定值后,它能使染料H聚集体分解成单分子,利于单分子光谱吸收;结果说明染料的荧光发射也随溶液中TAI浓度的增大而增强。本文还讨论了产生这种现象的原因。

【Abstract】 This study is about the influences of tetraazaindene(TAI) on absorption spectra and the fluorescence spectra of three kinds of sensitizing dyes.The absorption of all peaks of the dyes enhance with increasing TAI,among which the absorption of J aggregate has even marked enhancement.At certain value of TAI,the absorption of monomolecule of dye enhances much more rapidly as well as the absorption of H aggegte decreasing because of H aggregate dissociating into monomolecules.The results obtained also show that the fluorescence emissions of the dyes enhance with increasing TAI.The mechnisms of the observed phenomena are discussed in detail.

【基金】 国家自然科学基金
  • 【文献出处】 光谱学与光谱分析 ,SPECTROSCOPY AND SPECTRAL ANALYSIS , 编辑部邮箱 ,1997年01期
  • 【分类号】O657.31
  • 【被引频次】4
  • 【下载频次】28
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