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Fe(Ⅲ)-苯基荧光酮-溴化十六烷基三甲胺显色反应的研究与应用
Study on the Colour Reaction of Fe with PF and CTMAB and It’S Application
【摘要】 本文研究了在溴化十六烷基三甲胺存在下,苯基荧光酮与铁的显色反应。试验结果表明,显色的适宜酸度为pH等于7.3至10.5,配合物的摩尔吸光系数为1.09×105L·mol-1·cm-1,铁量在0-6μg·25mL-1范围内符合比耳定律。用于试样中铁的测定,灵敏度高,且简便可靠。
【Abstract】 In this paper, spectrophotometric determination of ferrum with phenyifluorone and cetyltrimethylammonium bromide is described. The molar absorptivity of the complex is 1. 09×105L. mo1-1.cm-1at 620nm. Beer’s Law is obeyed in the range of 0 to 6μg. 25mL-1 of Fe. Satisfactory resultshave been obtained when the coloration is used for determination of ferrum in water and copperminerals.
【关键词】 铁;
苯基荧光酮;
溴化十六烷基三甲胺;
显色反应;
【Key words】 Ferrum; Phenylfluorone (PF ); Cetyltrimethylammonium Bromide (CTMAB ); Colour Reaction;
【Key words】 Ferrum; Phenylfluorone (PF ); Cetyltrimethylammonium Bromide (CTMAB ); Colour Reaction;
- 【文献出处】 光谱实验室 ,CHINESE JOURNAL OF SPECTROSCOPY LABORATORY , 编辑部邮箱 ,1997年04期
- 【分类号】O657.3
- 【被引频次】4
- 【下载频次】38