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萘相萃取双波长分光光度法测定微量铜的研究
Study on DW-Spectrophotometric Determination of Microamounts Copper with Naphathalene-Phase Extraction
【摘要】 本文用萘作萃取剂,以5-Br-PADAP为显色剂,采用双波长分光光度法测定微量铜的研究。研究表明,选择540/383nm为测定波长时,组合物最大吸收峰为540nm,表观摩尔吸光系数为1.26×105L·mol-1·cm-1,铜量在0-5.0μg/7mL范围内符合比耳定律,方法应用于食品、水样品铜的测定,结果满意。
【Abstract】 In this paper,DW-spectrophotometric determination of Copper and by selecting naphathalene asthe soild extraction apent and the extracting complex of 5-Br-PADAP with Cu(Ⅱ ). Measuring wave-length and reference wavelength of 540/383nm. The maximum absorption of the complex is at 540nmand the molar absoprtwtty is 1. 26 × 10 5L· mol-1·cm-1. Beer’s. law is obeyed in the concentrationrange Cu (Ⅱ) 0- 5. 0μg/7mL. The proposed method has been appiled to the determination of Cu(Ⅱ) in water and food with satisfactory results.
【关键词】 双波长分光光度法;
铜;
5-Br-PADAP;
萘;
萘相萃取;
【Key words】 DW-Spectrophotometry; Copper (Ⅱ); 5-Br-PADAP; Naphathalene; Naphathalene-Phase Extraction;
【Key words】 DW-Spectrophotometry; Copper (Ⅱ); 5-Br-PADAP; Naphathalene; Naphathalene-Phase Extraction;
- 【文献出处】 光谱实验室 ,CHINESE JOURNAL OF SPECTROSCOPY LABORATORY , 编辑部邮箱 ,1997年02期
- 【分类号】O657.3
- 【被引频次】3
- 【下载频次】30