节点文献
PC/PBT共混体系的研究 Ⅰ.PC、PBT熔融共混时的酯交换反应
Studies of PC/PBT Blend System (Ⅰ) The transesterification taking place in molten blends of PC and PBT
【摘要】 采用红外光谱、核磁共振等测试手段,系统地研究了PC、PBT熔融共混时的酯交换反应,发现PBT中残余的Ti催化剂会对酯交换反应起催化作用。通过加入能和Ti催化剂络合的添加剂,可以控制酯交换程度,这为控制PC/PBT合金的性能提供了一个非常有效的方法。
【Abstract】 In this paper, the transesterification taking place in molten blends of PC and PBT was systematiclly studied by IR and 1 H NMR. The transesterification can be catalyzed by the titanium resedue presented in PBT and can be stopped at various levels by some additives capable of complexing the titanium catalyst. This provides a very useful method of controlling the properties of PC/PBT blends .
- 【文献出处】 功能高分子学报 ,JOURNAL OF FUNCTIONAL POLYMERS , 编辑部邮箱 ,1997年02期
- 【分类号】O631
- 【被引频次】28
- 【下载频次】498