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模拟热谱曲线法(Ⅲ)──可逆反应

Analog Thermogram Method(Ⅲ)──Reversible Reactions

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【作者】 张元勤曾宪诚胡启山孟祥光田安民

【Author】 ZHANG Yuan-Qin, ZENG Xian-Cheng, HU Qi-Shan,MENG Xiang-Guang, TIAN An-Min (Department of Chemistry, Sichuan University, Chengdu, 610064)

【机构】 四川大学化学系!成都610064达县师范专科学校!成都

【Abstract】 According to the theoretical bases of thermokinetics and analog thermogram method, a general analog thermogram method for several types of reversible reactions, with which the rate constants of forward and backward reactions and equilibrium constant can be calculted from the same thermogram simultaneously, has been proposed in this paper. The thermokinetics of the reactions of nitroethane with ammonia at 15℃ and 25℃ and with tris (hydroxymethyl)aminomethane at 15℃ and 30℃ have been studied with this method,re-spectively. The results of rate constants and equilibrium constants calculated with this method are in agreement with those in literatures. Therefore, the analog thermogram method for the reversible reactions is believed to be correct.

【基金】 国家自然科学基金
  • 【文献出处】 高等学校化学学报 ,CHEMICAL RESEARCH IN CHINESE UNIVERSITIES , 编辑部邮箱 ,1997年08期
  • 【分类号】O642
  • 【被引频次】8
  • 【下载频次】56
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