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羧甲基纤维素系列高分子表面活性剂超声合成的研究
A Study of Ultrasonic Copolymerization of Polymer Surfactants Based on Carboxy Methyl Cellulose
【摘要】 研究了在超声波作用下羧甲基纤维素(CMC)的降解反应及CMC与具有不同亲水亲油比值的活性大单体[烷基醇(酚)聚氧乙烯醚丙烯酸酯及第三单体(苯乙烯)]的超声共聚反应.经萃取提纯的共聚产物用IR、13CNMR和UV等方法进行表征,证实通过超声反应制得了二元和三元共聚物.超声反应时间及单体投料量对共聚物组成影响较大,共聚物具有较好的增粘能力和较高的表面活性.
【Abstract】 The copolymerization by ultrasonic irradiation of carboxy methyl cellulose(CMC)with macromonomer (alkyl poly (etheroxy) acrylate) and comono-mer(styrene) was studied.The purified products were characterized by IR, 13 C NMR and UV spectra, the results show that the copolymer prepared is mainly a block one. Ultrasonic irradiation time and monomer weight fraction in the feed have great influence on structure and properties of copolymers.Copolymers prepared by ultrasonic irradiation have a high viscosity and a good surface activi-ty.
【Key words】 Polymer surfactant; Ultrasonic synthesis; Carboxymethyl cellulose;
- 【文献出处】 高等学校化学学报 ,CHEMICAL RESEARCH IN CHINESE UNIVERSITIES , 编辑部邮箱 ,1997年06期
- 【分类号】O636
- 【被引频次】74
- 【下载频次】479