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TPR in situ (57)Fe MBS研究Fe/γ-Al2O3及Pt-Fe/γ-Al2O3催化剂

Studies of TPR in situ (57)Fe MBS on the Reduction Behavior of the γ-Al2O3 Supported Iron and Platinum-iron Catalysts

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【作者】 贾继飞沈俭一徐竹生葛欣张涛林励吾

【Author】 JIA Ji-Fei; SHEN Jian-Yit; XU Zhu-Sheng; GE Xint; ZHANG Tao;LIN Li-Wu(Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023;Department of Chemistry, Nanjing University, Nanjing, 210093)

【机构】 中国科学院大连化学物理研究所!大连116023南京大学化学系!南京210093

【Abstract】 The reduction behavior of Y-Al2O3 supported iron and platinum-iron catalysts was studied by TPR combined in situ 57Fe MBS. The results indicated that Fe3+ is highly dis-persed on the Y-Al2O3 surface for all the samples containing iron before the reduction. No Fe was found in the reduction process. The Fe3+ was reduced to Fe2+ in tetrahedral vacancy first in Pt-Fe/Y-Al2O3 sample in TPR process. The TPR processes of all supported iron samples are very different from those of α-Fe2O3.

【基金】 福特-中国研究与发展资助!094123O2;国家自然科学基金;国家教育委员会跨世纪人才基金
  • 【文献出处】 高等学校化学学报 ,CHEMICAL RESEARCH IN CHINESE UNIVERSITIES , 编辑部邮箱 ,1997年06期
  • 【分类号】O643
  • 【被引频次】2
  • 【下载频次】108
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