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含氮Ylide对C60的1,3-偶极环加成反应法合成含吡咯环C60衍生物
Synthesis of C60-Pyrrolidine Derivatives by 1,3-Dipolar Cycloaddition of Azomethine Ylides to C60
【摘要】 利用肌氨酸与对位含不同取代基的苯甲醛、共轭烯烃醛类及酮类反应生成的含氮Ylide对C60的加成反应,合成并分离、纯化制得了一系列含不同取代基的C60吡咯环纯衍生物,并用1HNMR、13CNMR、FDMS、FT-IR、UV-Vis等光谱手段确定了它们的分子结构.
【Abstract】 A series of different substituted azomethine Ylides were prepared through the reaction between sarcosine and different substituted benzoaldehydes, conjugated aldehydes and ketones. Further 1, 3-dipolar cycloaddition of these azomethine Ylides to C60 give rise to a series of new C60-pyrrolidine derivatives. The molecular structures of these compounds were ldent1fied and characterized by 1H NMR, 13C NMR, FDMS, FT-IR and UV-Vis spectro-scopies.
【关键词】 C60吡咯环衍生物;
肌氨酸;
含氮Ylide;
1,3-偶极环加成;
【Key words】 C60-Pyrrolidine derivative; Sarcosine; Azomethine ylides; 1; 3-Dipolar cycloaddition;
【Key words】 C60-Pyrrolidine derivative; Sarcosine; Azomethine ylides; 1; 3-Dipolar cycloaddition;
【基金】 国家攀登计划资助;国家自然科学基金;国家教育委员会优秀年轻教师基金
- 【文献出处】 高等学校化学学报 ,CHEMICAL RESEARCH IN CHINESE UNIVERSITIES , 编辑部邮箱 ,1997年05期
- 【分类号】O626
- 【被引频次】17
- 【下载频次】168