【摘要】 合成了β-苯基丙烯酸与稀土的14种配合物，经分析测定其组成为REL3（RE=Y，La～Yb，HL=β-C6H5CH＝CHCOOH）．用IR、NMR和单晶X射线衍射等技术对此类配合物的性质及晶体结构进行了研究．结果表明，ErL3为单斜晶系，P21空间群．在每个配位单元中，Er与来自6个羧酸根的7个氧原子配位，形成畸变的五角双锥配位多面体．更多还原

【Abstract】 Fourteen coordinattion compounds of lanthanide, β-phenylacrylate, were synthesized and characterized as REL3(RE=Y, La-Yb, HL=β-C6H5CH = CHCOOH) by chemical analysis, IR and NMR spectra and X-ray structure analysis. The crystal of ErL3 crystallizes in monoclinic system with space group P21. Each Er atom was coordinated with sevenoxygen atoms from six β-phenylacrylate groups forming a distorted pentagonal bipyramidconfiguration.更多还原