【摘要】 用超微电极研究了聚电解质聚乙二醇·高氯酸锂（ＰＥＧ·ＬｉＣｌＯ４）的电化学性能。用伏安法研究了气体、有机小分子、温度、支持电解质、聚合链长的影响。结果表明，有机小分子有增塑效应；物质的扩散速率随温度的上升而增加，随支持电解质中阳离子半径增大而增加，随聚合物链长增加而减小。用粘度和自由体积理论解释了此现象。定性地描述了电子自交换对扩散的贡献。更多还原

【Abstract】 This paper describes the properties of PEG polymer electrolyte as solvent medium for so1id-state voltammetry and results for the dependency of diffusive transport of electroac- tive solutes on organic small molecule, temperature, electrolyte and polymer chain length. The diffusion rate or the current response increases with increasing temperature and decreas- ing polymer chain length. This phenomenon is explained by free volume and viscosity theo- ry. The organic molecule exerts a greater“plasticizing” effect for polyelectroyte. The contri- bution of self electronic exchange is discussed qualitatively.更多还原