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流动注射停流-分光光度法同时测定痕量铝和铁
Simultaneous Determination of Aluminum and Iron by Flow Injection-Stopped Flow-Spectrophotometry
【摘要】 在弱酸性溶液中,基于铝、铁与铬天青S、溴化十六烷基吡啶形成蓝色三元络合物,采用两次标准加入法,建立了流动注射停流技术同时测定铝、铁的新方法。测定频率90次/h。铝、铁的线性范围分别为 0~0.4 mg/L和 0~0.8 mg/L。应用于水及食品中痕量铝、铁的测定,结果满意。
【Abstract】 A flow injection analysis with stopped flow technique for the simultaneous deter- mination of aluminum and iron is developed based on the formation of Al (Ⅲ), Fe (Ⅲ)- chrome azurol S-cetylpyridinium bromide blue ternary complex in weak acidic solution and double standard addition. The sampling rate is 90 samples/h. The linear range for Al(Ⅲ) is 0-0. 4 mg/L and for Fe(Ⅲ) is 0-0. 8 mg/L. The method has been applied to the determi- nation of Al (Ⅲ) and Fe (Ⅲ) in water and food with satisfactory results.
【关键词】 铝;
铁;
流动注射分析;
停流技术;
【Key words】 Aluminum; iron; flow injection analysis; stopped flow technique;
【Key words】 Aluminum; iron; flow injection analysis; stopped flow technique;
- 【文献出处】 分析化学 ,Chinese Journal of Analytieal Chemistry , 编辑部邮箱 ,1997年01期
- 【分类号】O657.3
- 【被引频次】27
- 【下载频次】124