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α-Al2O3 P/Al复合材料无压渗透制备反应加工机制的探讨

STUDY ON THE MECHANISM OF REACTIVE PROCESSING FOR THE FABRICATION OF α-Al2O3P/Al COMPOSITE BY PRESSURELESS METAL INFILTRATION

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【作者】 颜悦李秉哲吴逸贵彭应国张少卿

【Author】 Yan Yue Li Bingzhe~* Wu Yigui~* Peng Yingguo Zhang Shaoqing (Beijing Institute of Aeronautic Materials, Beijing 100095) (* Research Division for Composites, Luoyang Institute of Technology, Luoyang 471039)

【机构】 北京航空材料研究所洛阳工学院复合材料研究室北京航空材料研究所 北京 100095洛阳 471039北京 100095

【摘要】 本工作利用无压渗透法制备刚玉颗粒(α·Al2O3p)增强AlMg10合金复合材料,采用扫描电镜和EDS分析显微组织,并对无压渗透过程热力学研究,提出其反应加工机制:刚玉颗粒间隙内有限容积气氛(21%O2,79%N2),同熔融合金中铝(Al)镁(Mg)元素反应,形成固相,造成某种真空度,为无压渗透的驱动力。高温长时间条件下熔融基体AlMg10合金同刚玉颗粒和附加物的残留物发生化学反应。

【Abstract】 The study on the mechanism of reactive processing for the fabrication of α-Al2O3p/Al composite was performed by pressureless metal infiltration technique, optical micrography, SEM-micrography and EDS-analysis and thermodynamic consideration. This suggests the mechanism of reactive processing: the atmosphere of limited volume in vacancies between alundum particles (α-Al2O3p) could chemically react with Al-and Mg-element in the molten AlMg10 alloy infiltrated spontaneously into the preform of alundum particles, forming solid phases and a vacuum, i. e., a driving force for the infiltration; due to the long time contact between the molten AlMg10 alloy and alundum particles and additives, etc., at elevated temperatures, there might be chemical reactions.

【基金】 河南省自然科学基金;清华大学摩擦学国家重点实验室开放基金资助
  • 【文献出处】 复合材料学报 ,Acta Materiae Compositae Sinica , 编辑部邮箱 ,1997年01期
  • 【分类号】TB333
  • 【被引频次】7
  • 【下载频次】62
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