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12-钨硼杂多酸碱金属、碱土金属盐的合成及性质研究
Catalytic Activities of Polyoxometalates for Hydroxylation of Phenol
【摘要】 合成了12-钨硼杂多酸碱金属、碱土金属系列盐,对其红外光谱、紫外光谱、光电子能谱及其热性质进行了研究,并对其内外界盐的有关性质进行了比较
【Abstract】 The catalytic activities of polyoxometalates for hydroxylation of phenol have been investigated. H 6P 2W 18 O 62 and K 5 PW 11 O 39 Mn(H 2O) are found to be superior catalysts for the reaction. The conversion of phenol reaches 31 0% and 28 4%, respectively, and the selectivity of hydroquinone reaches 77 4% and 90 5%, respectively.
【关键词】 钨硼杂多酸;
碱金属;
热稳定性;
【Key words】 polyoxometalate; hydroxylation of phenol, catalytic activity, synthesis.;
【Key words】 polyoxometalate; hydroxylation of phenol, catalytic activity, synthesis.;
【基金】 国家自然科学基金
- 【文献出处】 东北师大学报(自然科学版) ,JOURNAL OF NORTHEAST NORMAL UNIVERSITY (NATURAL SCIENCE EDITION) , 编辑部邮箱 ,1997年02期
- 【分类号】TQ139.1
- 【被引频次】2
- 【下载频次】142