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聚合物固载Ni-Ag双金属催化剂Ⅲ.聚合物比表面积对催化剂分散度和活性的影响
POLYMER IMMOBILIZED SMAI Ni Ag BIMETALLIC CATALYSTS Ⅲ. Effects of the Specific Area of Polymer on Dispersion and Activity
【摘要】 聚合物固载NiAg双金属催化剂Ⅲ.聚合物比表面积对催化剂分散度和活性的影响吴世华朱常英黄唯平沈虎峻沈欣李连荣(南开大学化学系,天津300071)关键词镍,银,双金属催化剂,树脂,比表面积,固载型催化剂,加氢,燃料电池电极溶剂化金属原子浸渍(SMA...
【Abstract】 The solvated metal atom impregnation (SMAI) method was employed to prepare Ni Ag bimetallic catalysts immobilized with four kinds of resin of different specific area. The results of XRD and magnetic measurement showed that as the specific area of the resin increased, the particle size of Ni and Ag on the catalysts with the same metal content decreased, so the catalytic activity of the catalysts in hydrogenation of toluene and diacetone alcohol as well as in reduction of oxygen on the fuel cell electrode increased.
【关键词】 镍;
银;
双金属催化剂;
树脂;
比表面积;
固载型催化剂;
加氢;
燃料电池电极;
【Key words】 Nickel; Silver; Bimetallic catalyst; Resin; Specific area; Immobilized catalyst; Hydrogenation; Fuel cell electrode;
【Key words】 Nickel; Silver; Bimetallic catalyst; Resin; Specific area; Immobilized catalyst; Hydrogenation; Fuel cell electrode;
【基金】 国家自然科学基金
- 【文献出处】 催化学报 ,CHINESE JOURNAL OF CATALYSIS , 编辑部邮箱 ,1997年05期
- 【分类号】O643.36
- 【下载频次】137