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溴化N-(3-长链烷氧-2-羟)丙基-N,N,N-三甲基铵的合成及性质
Synthesis of N-(3-Long Chain Alkyloxy-2-Hydroxy)Propyl-N,N,N,-Trimethylammonium Bromide and Their Properties
【摘要】 脂肪醇和环氧氯丙烷在相转移条件下反应得到长链烷基缩水甘油醚,以此为原料和三甲胺氢溴酸盐反应得到溴化N-(3-长链烷氧-2-羟)丙基-N,N,N-三甲基铵。其结构通过红外光谱,核磁共振氢谱及元素分析结果得以证实。本文还测定所合成产品的表面张力和临界胶束浓度等。
【Abstract】 N-(3-long chain alkyloxy- 2 - hydroxy ) propyl-N, N, N-trimethyl ammonium bromide were synthesized from the reaction of trimethyl ammonium bromide and long chain alkyl glycidyl ether which were prepared from fatty alcohol and epichlorohydrim under a condition of phase transfer catalyst in a yield of 97%.Their structures were confirmed by IR,HNMR and elemental analyses. Surface tension and critical micelle concentration of the products were also determined in this paper.
- 【文献出处】 表面活性剂工业 ,SURFACTANT INDUSTRY , 编辑部邮箱 ,1997年02期
- 【分类号】TQ423
- 【被引频次】2
- 【下载频次】79