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溴化N-(3-长链烷氧-2-羟)丙基-N,N,N-三甲基铵的合成及性质

Synthesis of N-(3-Long Chain Alkyloxy-2-Hydroxy)Propyl-N,N,N,-Trimethylammonium Bromide and Their Properties

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【作者】 张广友赵淑英郑庚修赖永珩

【Author】 Zhang guangyou et al

【机构】 山东建材学院应用化学系!济南市250022

【摘要】 脂肪醇和环氧氯丙烷在相转移条件下反应得到长链烷基缩水甘油醚,以此为原料和三甲胺氢溴酸盐反应得到溴化N-(3-长链烷氧-2-羟)丙基-N,N,N-三甲基铵。其结构通过红外光谱,核磁共振氢谱及元素分析结果得以证实。本文还测定所合成产品的表面张力和临界胶束浓度等。

【Abstract】 N-(3-long chain alkyloxy- 2 - hydroxy ) propyl-N, N, N-trimethyl ammonium bromide were synthesized from the reaction of trimethyl ammonium bromide and long chain alkyl glycidyl ether which were prepared from fatty alcohol and epichlorohydrim under a condition of phase transfer catalyst in a yield of 97%.Their structures were confirmed by IR,HNMR and elemental analyses. Surface tension and critical micelle concentration of the products were also determined in this paper.

【关键词】 脂肪醇表面活性剂季铵盐
【Key words】 fatty alcoholsurfactantquaternary ammonium
  • 【文献出处】 表面活性剂工业 ,SURFACTANT INDUSTRY , 编辑部邮箱 ,1997年02期
  • 【分类号】TQ423
  • 【被引频次】2
  • 【下载频次】79
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