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HZSM-5催化剂上间二甲苯异构化反应动力学研究
Reaction Kinetics of m-Xylene isomeerization over zeolite hzsm-5
【摘要】 应用连续流动微反装置研究了HZSM-5分子筛上间二甲苯异构化反应动力学。通过计算机优化程序,求取了生成对二甲苯与邻二甲苯两个反应的表观速率常数之比及表现活化能之差。结果表明,对位选择性随温度降低而增大。
【Abstract】 The kinetic behavior of the isomerization of mxyline over zeolite HZSM5 has been studied by continuous flow microreactor. The ratio of apparent rate constants of mxylene converting into pxylene and oxylene has been calculated by using a computer optimum program. Also the difference of apparent activation energies between the above two processes has been calculated. The results showed that the paraselectivity for isomerization of mxylene increased with temperature decreasing.
【关键词】 ZSM-5分子筛;
间二甲苯;
异构化;
反应动力学;
表观速率常数;
表观活化能;
对位选择性;
【Key words】 zeolite ZSM5; mxylene isomerization; reaction kinetics; apparent rate constant; apparent activation energy; paraselectivity;
【Key words】 zeolite ZSM5; mxylene isomerization; reaction kinetics; apparent rate constant; apparent activation energy; paraselectivity;
【基金】 中国石化总公司资助
- 【文献出处】 北京化工大学学报(自然科学版) ,JOURNAL OF BEIJING UNIVERSITY OF CHEMICAL TECHNOLOGY , 编辑部邮箱 ,1997年04期
- 【分类号】O643.36
- 【被引频次】3
- 【下载频次】234