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D3-三高立方烷亚甲基上引入硝基的新方法
A New Method for Introducing Nitro Group into the Secondary Carbons of D3-Trishomocubane
【摘要】 报道了一种在D3-三高立方烷亚甲基上引入硝基的新方法.应用改进的维克托-迈耶反应,成功地将D3-三高立方烷-4,7-二醇(1)最终转化为4,7-二硝基D3-三高立方烷(3);将原有方法的五步反应缩短为两步反应,并将总得率由低于15%提高到近30%.
【Abstract】 A new method for introducing nitro group into the secondary carbons of D3-trishomocubane is reported. D3-Trishomocubane-4,7-diol(1) was successfully converted into 4,7-dinitro-D3-trishomocubane (3) by modified Victor-Mayer Reaction. The total yield was increased from 15% to 30% while the previous required 5 steps was reduced to 2 steps.
【关键词】 硝基;
亚甲基;
三高立方烷;
维克托;
迈耶反应;
【Key words】 nitro; methylene; trishomocubane; Victor-Mayer reaction;
【Key words】 nitro; methylene; trishomocubane; Victor-Mayer reaction;
- 【文献出处】 北京工业大学学报 ,Journal of Beijing Polytechnic University , 编辑部邮箱 ,1997年02期
- 【分类号】O625
- 【下载频次】70