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锌浴加镍对热镀锌层组织的影响
INFLUENCE OF ADDING Ni IN ZINC BATH ON THE MICROSTRUCTURE OF HOT DIP GALVANIZED COATING
【摘要】 利用SEM和EPMA研究了含0.22%Si钢板在含镍0.3%以下的几种锌浴中获得的镀层组织。研究结果表明:当锌浴含镍大于0.07%时,ζ相层变薄而晶粒细化,ζ相柱状晶的晶间和ζ相前沿的η相中出现镍富集;当锌浴中镍含量≥0.2%,在η相中析出ZnFeNi金属间化合物Γ2相的晶粒。文中还根据ZnFeNi三元相图,探讨了锌浴加镍后镀层组织变化的原因
【Abstract】 The microstructure of hot dip galvanized coatings of the steel sheet containing 0.22%Si by dipping in several zinc baths containing 0~0.3%Ni was studied by using SEM and EPMA. The result showed that, adding 0.07~0.12%Ni into the zinc bath, the ζ layer is thinned and the ζ crystal is fined, Ni is rich in the boundary of the columnar crystal of ζ layer and in the η phase in front of the ζ layer. Adding equal to or greater than 0.20%Ni into the zinc bath, some particles of Zn Ni Fe intermetallic compound are precipitated in the η layer. The reason that the coating microstructure is changed after adding Ni into the zinc bath is also discussed according to Zn Ni Fe ternary diagram.
【Key words】 hot dip Zn Ni alloy coating hot dip galvanizing Zn Ni Fe compound;
- 【文献出处】 中国有色金属学报 ,TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA , 编辑部邮箱 ,1996年04期
- 【分类号】TG15
- 【被引频次】31
- 【下载频次】158