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锌浴加镍对热镀锌层组织的影响

INFLUENCE OF ADDING Ni IN ZINC BATH ON THE MICROSTRUCTURE OF HOT DIP GALVANIZED COATING

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【作者】 卢锦堂陈锦虹许乔瑜曾广亮刘丽霞

【Author】 Lu Jintang, Chen Jinhong, Xu Qiaoyu, Zeng Guangliang, Liu Lixia Institute of Materials Science, South China University of Technology, Guangzhou, 510641

【机构】 华南理工大学材料科学研究所

【摘要】 利用SEM和EPMA研究了含0.22%Si钢板在含镍0.3%以下的几种锌浴中获得的镀层组织。研究结果表明:当锌浴含镍大于0.07%时,ζ相层变薄而晶粒细化,ζ相柱状晶的晶间和ζ相前沿的η相中出现镍富集;当锌浴中镍含量≥0.2%,在η相中析出ZnFeNi金属间化合物Γ2相的晶粒。文中还根据ZnFeNi三元相图,探讨了锌浴加镍后镀层组织变化的原因

【Abstract】 The microstructure of hot dip galvanized coatings of the steel sheet containing 0.22%Si by dipping in several zinc baths containing 0~0.3%Ni was studied by using SEM and EPMA. The result showed that, adding 0.07~0.12%Ni into the zinc bath, the ζ layer is thinned and the ζ crystal is fined, Ni is rich in the boundary of the columnar crystal of ζ layer and in the η phase in front of the ζ layer. Adding equal to or greater than 0.20%Ni into the zinc bath, some particles of Zn Ni Fe intermetallic compound are precipitated in the η layer. The reason that the coating microstructure is changed after adding Ni into the zinc bath is also discussed according to Zn Ni Fe ternary diagram.

  • 【文献出处】 中国有色金属学报 ,TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA , 编辑部邮箱 ,1996年04期
  • 【分类号】TG15
  • 【被引频次】31
  • 【下载频次】158
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