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钴铬复合氧化物超细微粒的制备、结构及其催化性能
Preparation,Structure and Catalytic Property of Cobalt Chromium Mixed Oxide Ultrafine Particle
【摘要】 钴铬复合氧化物超细微粒的制备、结构及其催化性能刘常坤,申永存,奚强(武汉化工学院精细化工系武汉430073)关键词钴铬复合氧化物,超细微粒,催化剂,制备,结构,催化氧化,三甲苯酚,三甲苯醌2,3,6-三甲苯酚(TMP)的氧化产物之一2,3,6-三甲苯...
【Abstract】 Cobalt chromium mixed oxide ultrafine particle catalysts were prepared by coprecipitation and sol-gel methods. The catalytic properties of catalysts for catalytic oxidation of 2,3,6-trimethylphenol to trimethyl-p-benzoquinone were investigated.It is shown that the catalyst with Co/Cr=1 prepared by sol-gel method is the best.The structures of catalysts were characterized by TEM,XRD and DTA-TG.The mixed oxide is amorphous under 350℃.The thermal stability of this amorphous catalyst is higher than that of Co3O4 and Cr2O3.
【关键词】 钴铬复合氧化物;
超细微粒;
催化剂;
制备;
结构;
催化氧化;
三甲苯酚;
三甲苯醌;
【Key words】 cobalt chromium mixed oxide; ultrafine particle; catalyst; preparation; structure; catalytic oxidation; trimethylphenol; trimethyl-p-benzoquinone;
【Key words】 cobalt chromium mixed oxide; ultrafine particle; catalyst; preparation; structure; catalytic oxidation; trimethylphenol; trimethyl-p-benzoquinone;
- 【文献出处】 应用化学 ,CHINESE JOURNAL OF APPLIED CHEMISTRY , 编辑部邮箱 ,1996年06期
- 【分类号】O643.36
- 【被引频次】4
- 【下载频次】92