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用硫脲溶液从载金树脂解吸金的动力学
KINETICS OF GOLD DESORPTION WITH ANION EXCHANGE RESIN
【摘要】 用硫脲溶液从载金P-950哌啶树脂解吸金的动力学研究表明,该解吸金的动力学符合Boyd液膜扩散方程,解吸金的速率随盐酸浓度的增加而下降;当温度上升时,解吸金的速率增加;提高硫脲浓度,有利于金的解吸。测得的液膜扩散系数K=4.24×10-4s-1,解吸表观活化能Ea=41.79kJ/mol。
【Abstract】 Kinetics of gold desorption with a new resin(P-950) in acidic thiourea solution was investigated.The experimental results demonstrated that the desorption of auric-thiourea com ̄plex fromthe resin can be describedbyBoyd’s diffusion equation of liquid film.The desorption rate of gold reducedremarkably with the increase of HCl concentration.The increace of thioureaconcentration and temperature accelerated the desorption of auric-thioureacom ̄plex.The distribution coefficient of the desorption K was4.24×10-4s-1 and the apparent activation energy of the desorption E awas 41.79kJ/mol.
【Key words】 anion exchange resin; auric-thiourea complex; desorption kineticsq;
- 【文献出处】 有色金属 ,NONFERROUS METALS , 编辑部邮箱 ,1996年04期
- 【分类号】O643.1
- 【被引频次】7
- 【下载频次】125