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三元共聚物SMAE醇解、胺解衍生物的合成及降凝性能
VISCOELASTIC EFFECT AND PRESSURE DISTRIBUTION OF POLYMER FLOODING SOLUTION IN RESERVOIR
【摘要】 在甲苯溶液中将苯乙烯马来酸酐丙烯酸高级醇(正十八碳醇、正十八至二十四碳混合醇)酯三元共聚物(SMAE)分别用正十八碳醇、正十八至二十四碳混合醇进行醇解,用正十八胺进行胺解,得到了一系列新聚合物,其红外光谱和凝胶渗透色谱法数据表明,醇解和胺解均发生在酸酐单元上。这些醇解和胺解衍生物对所测试的4种原油的降凝性能均比原始SMAE共聚物好,500ppm醇解和胺解衍生物使原油的凝固点下降20-31℃。
【Abstract】 The apparent shear viscosity μ v and effective viscosity μ ef in core flow for a modified polyacrylamide, PAM104A, solution of concentration 600 and 1000 ppm are determined and plotted verse apparent linear flow rate U (and shear rate , real or equvalent). μ ef is obtained from experimental values of resistance and residual resistance factors by using an aproximate equation. The difference between μ ef and μ v values denotes the elastic effect. Suggesting radial flow in reservoirs and using Darcys equation, flow pressure P i and flow rate U i (and eq ) of the polymer solution at distance R i from the polymer injection well borehole are determined. It is shown that at the experimental conditions the highest value of μ ef (and thus the most notable elactic effect) is observed where R i≤0.5m and the more the R i the higher the ΔP i(=P i P w where P w P i in borehole bottom) is and ΔP i becomes significant where R i is more than some 30m.
- 【文献出处】 油田化学 ,OILFIELD CHEMISTRY , 编辑部邮箱 ,1996年04期
- 【分类号】TQ2
- 【被引频次】24
- 【下载频次】182