【摘要】 光学活性生物分子的形成是世界进化历史中一个重要过程。“绝对”不对称合成,即在没有任何外界手性诱导试剂作用下或在圆偏振光影响下的封闭体系中的不对称合成,为前生物时期天然手性的成因提供了解释。本文将综述通过非手性分子形成的手性晶体的固相反应进行的“绝对”不对称合成。更多还原

【Abstract】 The formation of enantiopure optically active biomolecules is an important chapter in the history of evolution. "Absolute"asymmetric synthesis, i. e. an asymmetric synthesis carried out in a closed system without any external chiral inducing agents or with circularly polarized light, supports the explanations of how optical activity could have arisen under pre - biotic conditions. In the present review, we describe the asymmetric synthesis via the reactions of chiral crystals of achiral molecules.更多还原