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铋-邻氯苯基荧光酮-溴化十六烷基三甲铵显色反应的研究与应用
Study on the Colour Reaction of Bismuth with o-CPF and CTMAB and Its Application
【摘要】 研究了在pH9.25~11.0的缓冲溶液中,在溴化十六烷基三甲铵(CTMAB)存在下,Bi(Ⅲ)与邻氯苯基荧光酮(o-CPF)生成的紫红色络合物,其最大吸收波长为570nm,摩尔吸光系数为1.12×10 ̄5,Bi:o-CPF=1:3,铋量在0~30μg/25ml范围内符合比尔定律,用于测定钨矿中的铋,结果满意。
【Abstract】 In this paper, spectrophotometric determination of bismuth with o-chlorophenylfluorone and cetyltrimethylammonium bromide is described.The molar absorptivity of the complex is 1.12×10 ̄5 L·mol ̄(-1)·cm ̄(-1) at 570nmBeer’s law is obeyed in the range of 0-30μg/25ml for bismuth It has been to determine bismuth un trngsten ore with
- 【文献出处】 冶金分析 ,METALLURGICAL ANALYSIS , 编辑部邮箱 ,1996年04期
- 【分类号】O614.532
- 【被引频次】7
- 【下载频次】25