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超导体Y-Ba-Cu-O复合氧化物催化苯酚羟化反应的研究
Investigation of Catalysis of Y-Ba-Cu-O Mixed Oxides in Phenol Hydroxylation
【Abstract】 Superconductor Y-Ba-Cu-O mixed oxides were synthesized and their catalysis in phenol hydroxylation was studied too. Results show that, Y2BaCuO5 has better activity than that of YBa2Cu3O7-x, With the catalysis study of another mixed oxide La2CuO4 a conclusion that AO structure unit is the key for mixed oxides to have high activity in phyenol hydroxylation was drawn.Meanwhile,the effects of reaction temperature,medium and medium (water) pH on phenol hydroxylation catalyzed by Y2BaCuO5 and the stability of the mixed oxides were also studied.
【关键词】 复合氧化物;
苯酚羟化;
过氧化氢;
苯酚;
【Key words】 Mixed oxide; Phenol hydroxylation; Hydrogen peroxide; Phenol;
【Key words】 Mixed oxide; Phenol hydroxylation; Hydrogen peroxide; Phenol;
- 【文献出处】 物理化学学报 ,Acta Physico-chimica Sinica , 编辑部邮箱 ,1996年11期
- 【分类号】O643
- 【被引频次】1
- 【下载频次】44