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超导体Y-Ba-Cu-O复合氧化物催化苯酚羟化反应的研究

Investigation of Catalysis of Y-Ba-Cu-O Mixed Oxides in Phenol Hydroxylation

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【作者】 刘持标赵震杨向光叶兴凯吴越

【Author】 Liu Chibiao;Zhao Zhen;Yang Xiangguang;Ye Xingkai;Wu Yue(Changchun Institute of Applied Chemistry,Chinese Academy of Sciences, Changchun 130022)

【机构】 中国科学院长春应用化学研究所!长春130022

【Abstract】 Superconductor Y-Ba-Cu-O mixed oxides were synthesized and their catalysis in phenol hydroxylation was studied too. Results show that, Y2BaCuO5 has better activity than that of YBa2Cu3O7-x, With the catalysis study of another mixed oxide La2CuO4 a conclusion that AO structure unit is the key for mixed oxides to have high activity in phyenol hydroxylation was drawn.Meanwhile,the effects of reaction temperature,medium and medium (water) pH on phenol hydroxylation catalyzed by Y2BaCuO5 and the stability of the mixed oxides were also studied.

  • 【文献出处】 物理化学学报 ,Acta Physico-chimica Sinica , 编辑部邮箱 ,1996年11期
  • 【分类号】O643
  • 【被引频次】1
  • 【下载频次】44
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