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Tl2O3/聚-N-乙烯基咔唑复合纳米线的研究

Studies on Ordered Composite Nanowire Arrays of Tl2O3/Poly-N-vinylcarbazole

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【作者】 刘俊福杨孔章陆祖宏丁德胜吴海明

【Author】 Liu Junfu; Yang Kongzhang(Institute of colloid and Interface Chemistry,Shandong University,Jinan 250100)Lu Zuhong Ding Desheng Wu Haiming (National Laboratory of Molecular and Biomolecular Electronics,Southeast University,Nanjing210096)

【机构】 山东大学胶体与界面化学研究所!济南250100东南大学国家教委分子与生物分子电子学开放实验室!南京210096

【Abstract】 Stable monolayers of electropolymerized poly-N-vinylcarbazole (EPVK)and arachidic acid(AA) are obtained on a subphase of alkaline Tl2O3 colloidal solutions.As revealed by the atomic force microscope,there is phase separation in the mixed LB monolayers.Transmission electron microscopic observations reveal that oredred arrays of composite Tl2O3/Epvk nanowires are formed in the mixed monolayers.Formation of the composite nanowire arrays is attributed to the ordered adsorption of Tl2O3 colloidal particles along the polycationic EPVK chains.The composite nanowire array is 3.2nm wide with a spacing of 2.7nm.The composite nanowire arrays can also,be formed when pure EPVK is used.composite LB multilayers of Tl2O3/EPVK nanowire arrays are prepared.The bilayer spacing is 5054nm.The present study is of importance to the fabrication of inorganic semiconductor/functional polymer composite nanowires.

【基金】 国家自然科学基金;国家基础性研究重大项目
  • 【文献出处】 物理化学学报 ,Acta Physico-chimica Sinica , 编辑部邮箱 ,1996年10期
  • 【分类号】O626
  • 【下载频次】56
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