【摘要】 由混合二烃基二氯化锡 (RR′Sn Cl2 )与 2 -羟基 - 1 -萘醛缩苯胺类席夫碱反应 ,合成了 1 8种新的有机锡配合物。经元素分析 ,IR、1 H NMR、1 3 C NMR和 TG- DSC测定 ,确认配合物为有机锡与席夫碱的 1 2 1加成物 ,配体以酚羟基氧原子和锡原子配位。更多还原

【Abstract】 Eighteen new organotin complexes were synthesized by the reaction of mixed diorganotin dichlorides and corresponding 2 - hydroxy- 1- naphthalideneanilines. The synthesized adducts of1:1stoichiometry(mixed diorganotin dichloride:Schiff base) were characterized by elemental analysis,IR,1 H NMR,1 3 C NMR and TG- DSC. The ligands coordinate to tin atom via phenolic oxygen atom.更多还原