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竹叶花椒化学成分研究
STUDIES ON THE CHEMICAL CONSTITUENTS OF ZANTHOXYLUM ARMATUM DC.
【摘要】 从竹叶花椒(Zanlhoxylum armatum DC.)树皮中分离到13种化合物,经波谱(UV,IR,NMR,MS)分析及理化常数的对照,鉴定出其中的9种,它们是:β-白檀酮(β-amyrone)(Ⅱ),β-香木脂醇(β-amyrin)(Ⅱ),L-细辛素(L-asarinin)(Ⅳ),L-芝麻素(L-sesamin)(V).L-竹叶椒脂素(L-planinin)(Ⅵ),β-胡萝卜甙(β-daucosterol)(X),香草酸(Vanillic acid)(Ⅺ),β-谷甾醇(β-sitosterol)(Ⅻ),和一长链混合脂肪酸(二十四酸为主)(A mixed long-chain fatty acid)(Main in C24H48O2)(Ⅻ)。其中的晶Ⅱ和Ⅺ为首次从该属植物分离到,晶Ⅱ,Ⅴ,Ⅹ,Ⅺ和Ⅻ为首次从本植物分离到。 其余4种化合物正在鉴定中。
【Abstract】 Thirteen crystalline compounds were isolated from the bark of Zanthoxylam armatnm DC. , nine of them were identified as β-amyrone ( Ⅱ ),β- amyrin( Ⅲ),L -asarinin( Ⅳ ),L-sesamin(Ⅴ ),L-planinin ( Ⅵ ) ,β-daucosterol( Ⅹ ) ,vanillic acid( Ⅺ ) , β-sitosterol (Ⅻ ) and a mixed long-chain fatty acid (Ⅻ ) by means of spectral analysis and physical-chemical constants. The compounds of Ⅱ and Ⅺ were obtained for the first time from Zanthoxylum. The compounds of 2222 . Ⅴ,Ⅹ .Ⅸ and Ⅻ were isolated for the first time from this plant.The structure determination of compounds Ⅰ , Ⅶ,Ⅷ ,and Ⅸ is still in progress.
【Key words】 Znnthoxylam armatum armatam DC.; Amyrone; Triterpenoids; Bisepoxy lignans; Vanillic acid;
- 【文献出处】 天然产物研究与开发 ,Natural Product Research and Development , 编辑部邮箱 ,1996年04期
- 【分类号】O629
- 【被引频次】32
- 【下载频次】528