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烟煤快速加氢热解的研究Ⅰ.气氛影响的考察

STUDY ON FLASH HYDROPYROLYSIS OF BITUMINOUS COAL Ⅰ EFFECT OF ATMOSPHERES

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【作者】 朱子彬王欣荣马智华俞丰徐志刚张成芳黄瀛华

【Author】 Zhu Zibin Wang Xinrong Ma Zhihua Yu Feng Xu Zhigang Zhang Chengfang Huang Yinghua (East China University of Science and Technology, Shanghai)

【机构】 华东理工大学

【摘要】 在气流床快速热解装置上,系统地研究了内蒙东胜烟煤在氢气和氮气气氛中的快速热解行为。结果表明:在常压、700℃,煤在氢气氛中快速热解获得的液态烃的产率达2.6%,比在氮气氛中提高了80%,在6.0MPa的压力下,在氢气氛中的液态烃的产率是氮气氛的17倍;在常压、800℃时,在氢气氛中热解获得的甲烷产率达8.0%,比在同条件的氮气氛中提高了2.5倍,6.0MPa、700℃时,在氢气氛中的甲烷产率是氮气氛的5.3倍。烟煤在氢气氛中快速热解更有利于获取三苯(苯,甲苯,二甲苯)、三酚(苯酚,甲酚,二甲酚)和甲烷

【Abstract】 The flash pyrolysis of Dongsheng bituminous coal in H 2 and N 2 atmospheres were studied in a small entrained reactor The results showed that the yield of HCL (liquid hydrocarbon) produced in H 2 reached 2 6% at normal pressure and 700℃ which was 80% more than that produced in N 2 at the same condition. The yield of HCL in H 2 at 6 0MPa and 700℃ were 17 times larger than that produced in N 2 A large amount of free radical produced during coal pyrolysis can be fixed by hydrogen, so pyrolysis in H 2 can provide more HCL than pyrolysis in N 2 The yield of methane produced in H 2 was increased by 2 5 times of that produced in N 2 at normal pressure and 800℃ The yield of methane produced in H 2 was 4 3 times larger than that produced in N 2 at 6 0MPa pressure and 700℃ Production of methane needs enough hydrogen Pyrolysis in H 2 provides large amount of hydrogen for production of methane

【关键词】 烟煤热解气氛快速热解
【Key words】 bituminous coalpyrolysis atmosphereflash pyrolysis
【基金】 国家自然科学基金
  • 【文献出处】 燃料化学学报 ,JOURNAL OF FUEL CHEMISTRY AND TECHNOLOGY , 编辑部邮箱 ,1996年05期
  • 【分类号】TQ531.7
  • 【被引频次】32
  • 【下载频次】231
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