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载铁炭分子筛中铁的存在形态
STATES OF IRON SPECIES SUPPORTED ON CARBON MOLECULAR SIEVES
【摘要】 用M ssbauer谱法测定了载铁炭分子筛中铁的存在形态。结果表明,经焙烧和还原后,担载在炭分子筛上的Fe(NO3)3有75%~77%转变为Fe2O3,FeO,Fe(NO3)2和Fe3O4,其中有益于提高炭分子筛空分选择性的磁性Fe3O4的含量约29%.
【Abstract】 A study on the states of iron species supported on carbon mole cular sieves has been carried out with Mossbauer spectra. The result shows that through calcination and reduction 75%~77%of the Fe(NO3)3 supported on carbon molecular sieves is transformed into Fe2O3,FeO,Fe(NO3)2 and Fe3O4,in which the paramagnetic Fe3O4 takes a part of about 29%.
【关键词】 炭分子筛;
铁物类;
M ssbauer谱;
空分;
【Key words】 carbon molecular sieves; iron species; Mssbauer spectrum; air separation;
【Key words】 carbon molecular sieves; iron species; Mssbauer spectrum; air separation;
【基金】 国家自然科学基金
- 【文献出处】 煤炭转化 ,COAL CONVERSION , 编辑部邮箱 ,1996年01期
- 【分类号】TQ424.25
- 【被引频次】1
- 【下载频次】93