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无机三原子分子的离域π键和分子结构
Delocalization of Bonds and Molecular Constitutions of Inorganic Three-atomic Molecules
【摘要】 本文探讨了用群论和Huckel分子轨道法半定量处理无机三原子分子(或离子)的离域π健,求出它们的π分子轨道能级,并讨论它们的稳定结构及对分子磁性的解释。
【Abstract】 In this paper,We in a half quantitative way consider the delocalization of the π bonds of some inorganic threeatomic molecules (or ion ) in the light of the theory of groups and Huckel π-electron theory.The energy leves are given out for π molecular orbitals,and results are employed to explain the stable constitutlon and magnetic of these molecules.
【关键词】 三原子分子;
离域π键;
推断分子结构;
【Key words】 three-atomic molecule; delocalization of π bond; molecular constitution;
【Key words】 three-atomic molecule; delocalization of π bond; molecular constitution;
- 【文献出处】 吉首大学学报(自然科学版) ,Journal of Jishou University(Natural Science Edition) , 编辑部邮箱 ,1996年04期
- 【分类号】O641
- 【下载频次】126