【摘要】 本文利用d8（D1h）全组态混合统一晶场理论对Ni（PZ）4Cl2型化合物的吸收光谱、基态ZFS、EPR参量进行了统一的计算和理论分析，理论结果与实验一致。从而对其光、磁性质作出完整、合理、统一的解择。更多还原

【Abstract】 By means of a complete configuration mixing unified crystal field theory for d8(D4h),the optical spectra, the ground state ZFS、EPR parameters of Ni (PZ)4Cl2 compounds are analysed and calculated theoretically and systematically in this paper. All results agree well with the experimental data,so as to obtain a complete and teasonable explanation for the optical and magnetic properties of Ni (PZ)4Cl2 compounds.更多还原