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[PO3]-含量对掺Yb3+氟磷玻璃的光谱性质的影响
Dependance of Spectral Properties of Yb ̄(3+) on [PO3] ̄-Content in Fluorophosphate Glasses
【摘要】 实验研究了氟磷玻璃中[PO3]-含量的变化对Yb3+的光谱性质的影响。结果表明.随着[PO3]-含量的增大,Yb3+的受激发射截面积增大,吸收光谱和荧光光谱谱线位置向长波方向移动,反映出Nephelauxetic效应。随[PO3]-含量增大,玻璃中引入的OH-离子浓度增大,极大降低了Yb3+荧光寿命。
【Abstract】 The spectral Properties of Yb3+ are investigated in fluorophosphate gi ̄ withdifferent [PO3]- contentS. In fluorophosphate glasses the results indicate that as the [PO;]content increases in glasses; the stimulated emission cross section of Yb3+ increases; and theabsorption and emission Peaks shift to longer wavelengths;showing the Nephelauxeticeffect.Also; with the increase of [PO3]- content in the glass;more OH- exists in theglass;exertS strong influence on the fluorescence lifetime of Yb3+.
【关键词】 [PO3]-含量,Yb3+;
氟磷玻璃;
光谱性质;
【Key words】 PO3] ̄- content; Yb ̄(3+); fluorophosphate glass; spectral properties;
【Key words】 PO3] ̄- content; Yb ̄(3+); fluorophosphate glass; spectral properties;
【基金】 国家自然科学基金
- 【文献出处】 中国激光 ,CHINESE JOURNAL OF LASERS , 编辑部邮箱 ,1996年11期
- 【分类号】TN244
- 【被引频次】2
- 【下载频次】62