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东太平洋沉积物U的地球化学

GEOCHEMISTRY OF URANIUM IN DEEP SEA SEDIMENTS FROM EAST PACIFIC OCEAN

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【作者】 刘季花梁宏锋姚德高湘萍

【Author】 Liu Jihua Liang Hongfeng Yao De Gao Xiangping(Institute of Marine Geology,MGMR,Qingdao,266071,China)

【机构】 青岛地质矿产部海洋地质研究所

【摘要】 本文对地矿部“海洋四号”科学考察船1987—1989年在东赤道太平洋CC区所取得的27个深海表层沉积物样品进行U的地球化学分析,探讨了U在深海沉积中的地球化学行为。结果表明,不同类型沉积物的U含量不同,平均值由大至小的次序为含沸石粘土(2.16×10 ̄(-6))、硅质粘土(1.95×10 ̄(-6)),硅质软泥(1.65×10 ̄(-6))、钙质硅质粘土(1.59×10 ̄(-6)),在同类型沉积物中U的分散性较大;U在区域上的分布趋势与Corg类似而与CaCO_3相反,呈现出由南向北降低的趋势。与大陆边缘海、封闭、半封闭海的沉积物相比,深海沉积物的U含量最低,表现出U的亏损;U的晶体化学性质以及沉积物的物质来源决定了深海沉积物的U来源于海水和陆地,海水来源的U被自生粘土矿物和有机质吸附,陆源U与陆源粘土矿物有关,而较高的Eh和较低的Corg以及生物碎屑组份SiO_2、CaCO_3和P_2O_5对它起稀释作用都导致U的亏损,同时,U和Th较大程度的分异也是深海沉积物的主要标志。

【Abstract】 deep-sea sediment samples were collected in CC area by R/V“Haiyang Ⅳ” in northern East Pacific Ocean during 1987-1989.U contents in samples are detected by INNA method Based on the smear slide detection,the sediments are divided into four types:zeolitic clay siliceous clay,siliceous ooze and calcareous siliceous clay. U contents are different in these sediment types and are,on the arerage,2.16×10 ̄(-6) in zeolitic clay,1.95×10 ̄(-6) in siliceous clay,1.65×10 ̄(-6) in siliceous ooze and 1.59×10 ̄(-6) in calcareous-siliceous clay.In the same type of sediments,U has a higher variation coefficient than any other elements,indicating that U is dispersive in deep-sea sediments. The tendency of regional distribution is that U is higher in content in the northern part than in the south, which is similar to Corg and opposite to CaCO3.Compared with sediments from shelf and enclosed or semi-enclosed sea, deep-sea sediments have the lowest U contents. This fact shows U is in depletion in deep sediments. It is the feature of crystal chemistry of U,Th and the sources of deep-sea sediments that decides the U in deep-sea sediments to have two main sources:sea water and continent.Authigenic clay minerals such assmectite and organic materials absorb U from sea water while terrigenous clay mineralskeep U from land. High Eh and lower Corg and components associated with biogenicfragments as SiO2,CaCO3 and P2O5 all dilute U contents and make U depleted.Anotherimportant feature is that Th/U ratios are high in deep-sea sediments,which reflects astrong differentiation in CC area.

【基金】 国家自然科学基金
  • 【文献出处】 海洋地质与第四纪地质 ,MARINE GEOLOGY & QUATERNARY GEOLOGY , 编辑部邮箱 ,1996年01期
  • 【分类号】P736.45
  • 【被引频次】10
  • 【下载频次】71
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