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3-硝基-4-溴-1,8-萘二甲酸酐与己胺的反应
REACTION OF 3 NITRO 4 BROMO 1,8 NAPHTHALIC ANHYDRIDE WITH HEXYLAMINE
【摘要】 3-硝基-4-溴-1,8-萘二甲酸酐与己胺的反应柳波沈永嘉*董黎芬(华东理工大学精细化工研究所,上海,200237)关键词合成结构表征1,8-萘二甲酰亚胺1,8-萘二甲酰亚胺是一类良好的荧光发色体,其4位上有供电子基团的衍生物大都具有强烈的荧光,已被...
【Abstract】 The product of the reaction of 3 nitro 4 bromo 1,8 naphthalic anhydride with hexylamine in ethanol is N hexyl 3 nitro 4 hexylamino 1,8 naphthylimide.This result shows that a bromo group in 4 position becomes very reactive due to an electron drawing nitro group on β position of the anhydride which is therefore capable of reacting with hexylamine easily,even in the absence of copper catalyst and under ordinary pressure.
【关键词】 合成;
结构表征;
1;
8-萘二甲酰亚胺;
【Key words】 Synthesis; characterization of structure; N hexyl 3 nitro 4 hexylomino 1; 8 naphthylimide;
【Key words】 Synthesis; characterization of structure; N hexyl 3 nitro 4 hexylomino 1; 8 naphthylimide;
- 【文献出处】 化学研究与应用 ,CHEMICAL RESEARCH AND APPLICATION , 编辑部邮箱 ,1996年03期
- 【分类号】TQ226.31
- 【被引频次】2
- 【下载频次】456