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长叶烯通过异构化、氧化和Prins反应合成新型香料
THE SYNTHESIS OF NEW ODOROUS SUBSTANCES BY ISOMERIZATION,OXIDATION & PRINS REACTION OF LONGIFOLENE
【摘要】 本文报道综合利用长叶烯(1)催化异构化为异长叶烯(2)及合成系列香料的方法;通过氧化反应合成不同香型烯醇酯类等;Prins反应合成系列化合物。鉴定了10种香料化合物的香型。
【Abstract】 The methods of synthesis of isolongifolene from longifolene by the catalyzing isomerization and the formating of odorous substances were reported.The different fragnant enol esters were synthesized by the oxidating reaction and some odorous substances that are useful in future were synthesized by the Prins reaction.Ten pieces of odorous substances were defined.
【关键词】 长叶烯;
异构化;
氧化;
prins反应;
合成;
香料;
【Key words】 Longifoene; Isomerization; Oxidation; Prins reaction; Synthesis; Odorous substances;
【Key words】 Longifoene; Isomerization; Oxidation; Prins reaction; Synthesis; Odorous substances;
- 【文献出处】 化学研究与应用 ,CHEMICAL RESEARCH AND APPLICATION , 编辑部邮箱 ,1996年03期
- 【分类号】TQ655
- 【被引频次】6
- 【下载频次】213