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四氢呋喃阳离子聚合向丁二酸酐链转移反应的研究
STUDING OF THE CHAIN TRANSFER REACTION OF THE TETRAHYDROFURAN CATIONIC POLYMERIZATION TO SUCCINIC ANHYDRIDE
【摘要】 四氢呋喃阳离子聚合向丁二酸酐链转移反应的研究魏斌,赵庆香,栗方星(南开大学化学系天津300071)关键词聚四氢呋喃,五氯化锑,表现链转移速率常数,表现聚合反应速率常数前言在用CH3COSbCl5引发的四氢呋喃阳离子聚合[1]过程中,我们发现存在着活性...
【Abstract】 In the tetrahydrofuran cationic polymerization initiated by CH-3OCSbCl5,the chain transfer reaction from active center to succinic anhydride is found. The apparent chain transfer rate constant ktr for the chain transfer reaction and the apporent pohymerization rate constant kp are determined. In the Paper,we also investigate the influence of the chain transfer on the polytetrahydrofuran tensile strength and the potential value for the exploitation.
【关键词】 聚四氢呋喃;
五氯化锑;
表现链转移速率常数;
表现聚合反应速率常数;
【Key words】 Polytetrahydrofuran; SbCl5; Apparent chain transfer rate constant; Apparent polymerization rate constant;
【Key words】 Polytetrahydrofuran; SbCl5; Apparent chain transfer rate constant; Apparent polymerization rate constant;
- 【文献出处】 化学研究与应用 ,CHEMICAL RESEARCH AND APPLICATION , 编辑部邮箱 ,1996年02期
- 【分类号】O631.5
- 【下载频次】81