【摘要】 Ｎｄ（ＣＣｌ_３ＣＯＯ）_３（Ｐｈｅｎ）_２和［Ｅｕ（ＣＣｌ_３ＣＯＯ）_２（Ｐｈｅｎ）_２２Ｈ_２Ｏ］^＋［ＣＣｌ_３ＣＯＯ］^－的电子结构和化学键成义祥，王培筠，陆维敏，董南（杭州大学化学系杭州３１００２８）关键词ＩＮＤＯ，稀土混配配合物，电子结构，化学键...更多还原

【Abstract】 The electronic structure and chemical bond in the comlexes Nd （CCl₃COO）₃)Phen)₂ and[Eu（CCl₃COO）₃（Phen）₂2H₂O] have been studied by INDO method.The results indicated that the bonds between Lanthanide ions and oxygen or nitrogen atoms are main clue to the participation of RE（5d） orbitals,and to the leaser extent,RE（6s） and RE（6p） orbitals,the 4f orbitals hardly have contribution in all covalence orbitals of Nd or Eu.更多还原