【摘要】 本文用三苯基氢化锡、三对甲苯基氢化锡作为锡氢化试剂与1-乙炔基环辛醇进行反应,合成了两个有机锡化合物:[Z]-1-[2-（三苯基锡基）乙烯基]环辛醇（1）和[Z]-1-[2-（三对甲苯基锡基）乙烯基]环辛醇（2）,并测定了1的晶体结构.1和2分别与ICl,Br₂,I₂反应,得到六个有机锡一卤化物和三个有机锡二卤化物（3～11）.有机锡二卤化物6和一卤化物5与KOH乙醇溶液反应,分别得到相应的锡氧化物和锡氢氧化物（12,13）.有机锡二卤化物8分别与含氮双齿配体[2,2-联吡啶（Bipy）,5-硝基-1,10-邻菲罗啉（Nphen）,8-羟基喹啉（Oxin）]反应,得到三个相应的配合物（14～16）.十六个新化合物通过元素分析、锡含量测定、IR、¹HNMR测定对其结构进行了表征,同时提出了1和2的生成反应历程.更多还原

【Abstract】 The compounds of[Z]-1-[2- (triphenyl stannyl) vinyl] cyclooctanol (1) and [Z] -1-[2-(tri -p- tolyl stannyl) vinyl] cyclooctanol (2) were synthesized by the reactions of triphenyltin hydride and tri - p - tolyltin hydride with 1 - ethynyl cyclooctanol. The crystal structure of compound 1 was determined. The reactions of compound 1 and 2 with IC1, Br2, I2 formed nine organotin halides. The organotin oxide or hydroxide were prepared by the reactions of [Z]-1-[2- (phenyl dibromo stannyl) vinyl] cyclooctanol (6) and [Z]-1-[2- (diphenyl monobromo stannyl) vinyl]cyclooctanol (5) with KOH. Three complexes were obtained by the reactions of [Z]-1 - [2 - (phenyl diiodide stannyl) vinyl] cyclooctanol (8) with three ligands (2,2’- bipyridyl , 5 - nitro -1,10 - phenanthroline, 8 - Hydroxyquinoline).The sixteen new compounds synthesized in this paper were characterized by means of elemental analysis, IR,1H NMR. The reaction mechanism of triphenyltin hydride and tri - p -tolyltin hydride with 1 - ethynyl cyclooctanol were also proposed.更多还原