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Ni(mpz)4X2(X=Cl,Br,I)型化合物光磁性质的理论研究
Theoretical Research on Optical and Magnetic Properties of The Ni(mpz)4I2 (X=Cl, Br,I) Compounds
【摘要】 利用d8(D4h*)全组态混合统一晶场理论对Ni(mpz)4X2型化合物光谱、零场分袭(ZFS)、(DPR)参量、顺磁磁化率进行了统一的理论计算,理论结果与实验观测值吻合较好.因此对该化合物的光、磁性质作出了完全统一的理论解释.
【Abstract】 By means of complete configuration mixing unified theory for d2,3(D*2h),the optical absorption spectrum,the ground state zero-field spliting parameters,the EPR parameters and the magnetic susceptility of the compounds Ni (mpz)4X2 have been calculated theortically and uniformly.This results agree with the experimental values basically, therefore we explained the optical and magnetic properties of the compounds the oretically and completely uniformly.
【关键词】 Ni(mpz)2X2型化合物;
光谱;
顺磁磁化率;
D2h点群对称性;
【Key words】 Ni(mpz)4X2 compounds; spectrum; susceptibility; D2h point group symmetry;
【Key words】 Ni(mpz)4X2 compounds; spectrum; susceptibility; D2h point group symmetry;
【基金】 湖南省自然科学基金
- 【文献出处】 湖南师范大学自然科学学报 ,ACTA SCIENTIARUM NATURALIUM UNIVERSTIS NORMALIS HUNANENSIS , 编辑部邮箱 ,1996年02期
- 【分类号】O657
- 【下载频次】9