节点文献

双极性膜电渗析法在脱硫废液NaHSO3再生过程中的应用研究

Study on the Regeneration or NaHSO3 In the Recovery of SO2 from Flue Gas by Bipolar Membrane Electrodialysis

  • 推荐 CAJ下载
  • PDF下载
  • 不支持迅雷等下载工具,请取消加速工具后下载。

【作者】 余立新孟昭辉林爱光蒋维钧

【Author】 Yu Lixin et al.(Department of Chemical Engineering,singhua University, Beijing 100084)

【机构】 清华大学化学工程系

【摘要】 介绍了用双极性膜电渗析法对烟气脱硫废液(NaHto3)进行再生的方法.使用自制均相双极性膜和上海产界相双极性膜,配以均相阳离子交换膜,均能以满意的转化率(80%以上)实现再生.再生过程中电流效率的下降(由80%左右下降到20%左右)是由于酸室中氢离于浓度升高所致.脱硫废液中少量硫酸钠的存在对再生过程无明显影响.目前阻碍该法实际应用的主要问题是国内试制膜的寿命较短.

【Abstract】 ipolar membrane electredialysis is adOPted in the regeneration of NaHSO3, which is used as absorbent of SO2from flue gas.When canon-exchange membrane is supplemented with, both homogeneous and heterogeneous biPOlar m6mbranes which are made in our lab and by Shanghai Chemical Factory, respectively,can produce satisfactory conversion ratio (higher than 80%)in the regeneration process. The decrease of current efficiency (from approximately 80% to approximatdy 20%)is resulted from the increase of the concentration of proton in acid chamber.The existence of small amount of Na2So4in NaHSO4 solution doesn’t cause much effeCt on regeneration process.The short membrane lifetime hinders the process from getting into practical application.

【基金】 煤的清洁燃烧国家重点实验室课题
  • 【文献出处】 环境科学 ,CHINESE JOURNAL OF ENVIROMENTAL SCIENCE , 编辑部邮箱 ,1996年06期
  • 【分类号】TQ028.74
  • 【被引频次】23
  • 【下载频次】208
节点文献中: 

本文链接的文献网络图示:

本文的引文网络