节点文献
纯液体表面张力的统计热力学模型
STATISTICAL THERMODYNAMIC MODEL FOR CALCULATION OF SURFACE TENSION OF PURE LIQUIDS
【Abstract】 two equations for the calculation of surface tension of pure liquids are derived based on statistical thermodyanics by expressing the intermolecular potential as lennard-Jones pair potential.This method is simple,accurate and easy to use.The calculation results for the 22 pure liquids show that these equations are superior to the empirical forula and other theoretical equations.The average relative deviations for these two equations are within 5% and 1.5% respectively.
【关键词】 表面张力;
统计热力学;
Lennard-Jones位能;
径向分布函数;
【Key words】 surface tension; statistical thermodynamics; Lennard-Jones potential; radial distribution function;
【Key words】 surface tension; statistical thermodynamics; Lennard-Jones potential; radial distribution function;
【基金】 国家自然科学基金
- 【文献出处】 化工学报 ,Journal of Chemical Industry and Engineering(China) , 编辑部邮箱 ,1996年03期
- 【分类号】O647
- 【被引频次】17
- 【下载频次】704