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PA6─PEO二胺─BAPA嵌段共聚型抗静电剂共混改性涤纶的研究

ANTISTATIC MODIFICATION OF POLYESTER FIBER BLENDED WITH PA6-PEO DIAMINE-BAPA BLOCK COPOLYMER

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【作者】 赵耀明; 陈军武; 黄兹国; 吴珣;

【Author】 Zhao Yaoming; Chen Junwu; Huang Ziguo and Wu Xun (Department of Polymer Material Science & Engineering South China University of Technology)

【机构】 华南理工大学高分子材料科学与工程系;

【摘要】 在少量水存在下,将聚氧乙烯二胺(PEO二胺)及N,N-二(3-氨丙基)甲胺(BAPA)与等摩尔的己二酸成盐后,再与己内酰胺共聚制得PA6-PEO二胺-BAPA嵌段共聚物,然后将共聚物与PET切片进行共混熔融纺丝、拉伸,得到PET/PA6-PEO二胺-BAPA共混改性纤维。研究发现,嵌段共聚物中低聚物含量少,改性纤维具有良好的可纺性、拉伸性及较高的强度保持值,共混纤维的抗静电性优良,还同时具有分散染料和酸性染料的可染性。对改性纤维进行季铵化处理后,可获得更加优越的抗静电效果。

【Abstract】 With a little amount of water, poly(oxyethylene)diglycolic amine(PEO diamine)and N,N-bis(3-aminopropyl)methyl amine (BAPA)formed salts with equal moles of adipic acid, then copolymerized with caprolactam and PA6-PEO diamine-BMA block copolymers were prepared. The block copolymer pellets were mixed with PET pellets, and the PET/PA6-PEO diamine-BAPA blend fiber was obtained by melt spinning and drawing. The spinnability and the drawability were quite good. The modified fibers had very good antistantic property while their tensile strength was close to that of PET fiber. The blend fibers could be dyed in disperse and acid dyeing systems,After the quaternary ammonium treatment,the modified fiber had much better antistaic property .

  • 【文献出处】 合成纤维工业 ,CHINA SYNTHETIC FIBER INDUSTRY , 编辑部邮箱 ,1996年04期
  • 【分类号】TQ342.204
  • 【被引频次】4
  • 【下载频次】151
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