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用阳离子乳化剂的丙烯酸丁酯-苯乙烯共聚合
EMULSION COPOLYMERIZATION OF BUTYL ACRYLATE AND STYRENE USING CATIONIC SURFACTANT AS EMULSIFIER
【摘要】 采用4种阳离子乳化剂,以过硫酸钾为引发剂合成了丙烯酸丁酯(BA)─苯乙烯(St)共聚物乳液。考察了乳化剂种类、聚合条件及加料方式对共聚合及乳液稳定性的影响,发现乳化剂十二烷基二甲基苄基氯化铵用量为2.0%时,BA─St共聚物的[η]和乳液粘度出现拐点现象。
【Abstract】 The emulsion copolymerization of butyl acrylate(BA)and styrene(St)using cationic sufactant as emulsifier was studied.The effects of the type and amount of emulsifier,polymerization temperature and feeding order of materials on quality of the emulsion and yield[η]of copolymer were investigated.
【关键词】 阳离子乳化剂;
乳液聚合;
丙烯酸丁酯-苯乙烯共聚物;
【Key words】 cationic emulsifier; emulsion polymerization; butyl acrylate and styrene copolymer;
【Key words】 cationic emulsifier; emulsion polymerization; butyl acrylate and styrene copolymer;
- 【文献出处】 合成橡胶工业 ,CHINA SYNTHETIC RUBBER INDUSTRY , 编辑部邮箱 ,1996年03期
- 【分类号】O632.52
- 【被引频次】3
- 【下载频次】235