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草酸二乙酯催化加氢制乙二醇模试研究
Simulation Test on Catalytic Hydrogenation of Diethyl Oxalate to Ethylene Glycol
【摘要】 本文简要介绍草酸二乙酯催化加氢制乙二醇的模试结果。在温度200~240℃,压力0.6~3.0MPa条件下,草酸二乙酯的转化率为99.8%,产率达到95.3%,催化剂连续运转1134h,活性和选择性仍无下降趋势。
【Abstract】 Results of simulation text for catalytic hydrogenation of diethyl oxalate to ethylene glycol are reported in this article. Under 0. 6-3. 0 MPa and at 200-240 C, a diethyl oxalate conversion of over 99% and selectivity of 95. 3% to ethylene glycol was achieved on Ec-13 catalyst. No decrease in catalytic activity and selectivity was observed in 1134 hours of hydrogenation reaction.
【关键词】 草酸二乙酯;
乙二醇;
催化加氢;
模试;
【Key words】 diethyl oxalate; ethylene glycol; catalytic hydrogenation; simulation test;
【Key words】 diethyl oxalate; ethylene glycol; catalytic hydrogenation; simulation test;
【基金】 国家“八五”科技攻关项目
- 【文献出处】 工业催化 ,GONGYE CUIHUA (INDUSTRIAL CATALYSIS) , 编辑部邮箱 ,1996年04期
- 【分类号】TQ225.241
- 【被引频次】70
- 【下载频次】708