【摘要】 ｍｅｓｏ－苯基四苯并卟啉锌的合成和光谱性能的研究胡敏学，王夺元（中国科学院感光化学研究所，北京１００１０１）关键词ｍｅｓｏ－苯基四苯并卟啉，高温缩合反应，吸收光谱，振子强度，聚集作用四苯并卟啉（ＴＢＰ）及其金属配合物是一类新型的光敏性分子，其０－０跃...更多还原

【Abstract】 In this paper,the preparation of meso-phenyl substituted tetrabenzoporphyrinato-zinc by an improved synthetic procedure are described. After purification,four pure compounds (Zn-PnTBP n = 1￣4) are obtained. Their absorption spectra are determined,and the reason of discrepant data for same compound appeared in references is explained. In addition,the effects of solvent polarity and pyridine content on the Soret and Q absorption spectra of Zn-P2 TBP are discussed.更多还原