节点文献
固相反应合成卟啉类配合物
Synthesis of Lanthanide Porphrin Coordination Compounds by Solid State Reaction
【摘要】 固相反应合成卟啉类配合物刘国发,滕永富,师同顺(吉林大学化学系,长春,130023)关键词乙酰丙酮,四苯基取代卟啉,四萘基四苯并卟啉,稀土配合物镧系卟啉配合物是通过在高沸点溶剂或熔融咪唑中反应并进行较为复杂的分离和纯化后而得到的[1].由于合成条件苛...
【Abstract】 Synthesis of lanthanide porphyrin coordination compounds was described.The coordination compounds contain acetylacetonate-5,10,15,20-tetraphenylporphyrin ybtterbium,acetylacetonate-5.(p-hydroxyphenyl)-10,15,20-tri(p-methoxyphenyl) porphyrin lutetium acetylacetonate-5,10,15,20(p-methoxyphenyl) porphyrin europium and acetylacetonate5,10,15,20-(p-naphthyl)-tetra-benzoporphyrin erbium,The coordination compounds were characterized by elementary analysis, UV-Vis,IR spectra and 1 ̄H NMR spectra.
【关键词】 乙酰丙酮;
四苯基取代卟啉;
四萘基四苯并卟啉;
稀土配合物;
【Key words】 Acetylacetone; Tetraphenylsubstituted porphyrin; Tetranaphthyl tetrabenzoporphyrin; Rare earth complex;
【Key words】 Acetylacetone; Tetraphenylsubstituted porphyrin; Tetranaphthyl tetrabenzoporphyrin; Rare earth complex;
- 【文献出处】 高等学校化学学报 ,CHEMICAL RESEARCH IN CHINESE UNIVERSITIES , 编辑部邮箱 ,1996年07期
- 【分类号】O626.13
- 【被引频次】8
- 【下载频次】101