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不溶性单分子膜中碳氢、碳氟表面活性剂分子间相互作用
The Interaction Between Fluorocarbon and Hydrocasrbon Surfactants in mixed Mixed Monolayers
【摘要】 考虑到吸附膜与单分子不溶膜的相似性,在不溶膜研究中引入分子间相互作用参数β,用以讨论不溶膜中的非理想性问题.对“6201”/C_(18)SO_4Na体系得到了一个与临界值2.0接近的β值,进一步验证了该体系存在相分离的推测.
【Abstract】 In consideration of the similarity of insoluble monolayers and soluble monolayers,amolecular interaction parameter(β)was introduced to describe the nonideality of the mixedinsoluble monolayers. From the surface pressure-area isotherms of “6201”/C18SO4Na mix-tures,a high molecular interaction parameter which was closed to the critical value 2.0 wasobtained,which has further verified the previous guess that a phase separation took place ata higher surface pressure.
【关键词】 不溶单分子膜;
分子间相互作用多数;
非理想性;
表面活性剂;
【Key words】 Insolube monolayers; Intermolecular interaction parameter; Nonideality; Sur-factant;
【Key words】 Insolube monolayers; Intermolecular interaction parameter; Nonideality; Sur-factant;
【基金】 国家自然科学基金
- 【文献出处】 高等学校化学学报 ,CHEMICAL RESEARCH IN CHINESE UNIVERSITIES , 编辑部邮箱 ,1996年01期
- 【分类号】O647.2
- 【被引频次】14
- 【下载频次】173