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水杨醛苯腙与铜荧光反应的研究及其应用

Studies on Fluotimetrid Reaction of Salicylaldehyde Benzalhydrazone with Copper and Its Application

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【作者】 江崇球唐波傅红燕曹红张晓刚

【Author】 JIANG Chong-Qiu;TANG Bo;FU Nong-Yan;CAO Hong;ZHANG Xiao-Gang(Department of Chemistry,Shandong Teacher’s University ,Jinan, 250014)

【机构】 山东师范大学化学系

【摘要】 水杨醛苯腙与铜荧光反应的研究及其应用江崇球,唐波,傅红燕,曹红,张晓刚(山东师范大学化学系,济南,250014)关键词铜,水杨醛苯腙,荧光分析胺类试剂是一类理想的荧光分析试剂[1],用其测定Al3+[2]、Ga3+[3]、Zn2+[4]已显示出其灵敏...

【Abstract】 A new fluorimetric reagent, salicylaldehyde benzalhydrazone has been established.The fluorimetric reaction of the reagent with copper was carried out in aqueous medium at pH=9.0 and studied in detail. The fluorescence excitation and emission wave-lengthsof the complex are 300 nm and 410 nm respectively. The linear range is 0.0~0.8 μm/10mL,the detection limit is 12. 4 ng/mL and the molar ratio of copper to the reagent is 1:1.The method has been applied to the determination of trace copper in tea and hair with satisfactory results.

【关键词】 水杨醛苯腙荧光分析
【Key words】 CopperSalicylaldehyde benzalhydrazoneFluorimetry
  • 【文献出处】 高等学校化学学报 ,CHEMICAL RESEARCH IN CHINESE UNIVERSITIES , 编辑部邮箱 ,1996年01期
  • 【分类号】O614.121
  • 【被引频次】25
  • 【下载频次】297
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