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光化学动力学分光光度法测定柠檬酸
Photochemical Kinetics/Spectrophotometric Determinaiton of Trace Citric Acid
【摘要】 本文基于柠檬酸可以加速铁(Ⅲ)-邻菲罗啉还原为铁(Ⅱ)-邻菲罗啉溶液体系的光化学反应.建立了光化学动力学光度法测定柠檬酸的新方法。测定范围0~15mg柠檬酸/L,检出限达0.32mg/L。直接用于汽水中柠檬酸的分析,结果满意。
【Abstract】 A new method for determination of citric acid is dcveloped. It is based on thecatalytic effect of citric acid on the reduction of Fe (Ⅲ )-1, 10-phenanthroline to Fe (Ⅱ ) 1’ 10phenanthroline under irradiation in aceticacid-sodium acetate medium . The linear range ofdetermination for citric acid is 0~ 1 5 mg/l, and the detcction limit is 0. 32 mg/L. Satisfactory results were obtained for direct determination of citric acid in aerated water.
- 【文献出处】 分析化学 ,Chinese Journal of Analytieal Chemistry , 编辑部邮箱 ,1996年11期
- 【分类号】O657.3
- 【被引频次】11
- 【下载频次】232